Poly(styrene-alt-maleimide) (SMI) is a cationic polyelectrolyte soluble in acidic solution, having a pH<3. This alternating copolymer is expected to self-assemble in similar structures as SMA, which Cecile Malardier worked on. SMI was shown to self-associates into ordered nano-structures and were characterized by AFM of dilute solutions (< 1%). At pH 1-2, ring shaped structures, diameter of 70nm and height 15nm were observed, while at pH 3, linear structures with random curves and bifurcations were observed: 1nm long and 10nm high. Molecular Modelling helps understand the self-assembly of these polymers and predict the dimensions of the nanostructures.
Whitehead group
Contacts
address:
Prof. M.A. Whitehead
Department of Chemistry
McGill University
Otto Maass Chemistry Building,
801 Sherbrooke St. West,
Room 352,
Montreal, Quebec,
H3A 2K6, Canada.
Phone:
office: (514) 398-6239
lab: (514) 398-6905
fax: (514) 398-3797
email:
tony.whitehead@mcgill.ca